Experiment 19: Kinetics : the Rate of an Experiment

March 17, 2013 March 17, 2013 bring in Ryan annasdass arokiasamy ID 1206875 Group Members Chan Pei Qie,Chong Ven Yen Name Ryan annasdass arokiasamy ID 1206875 Group Members Chan Pei Qie,Chong Ven Yen experiment 19 kinetics the study of a chemical answer experiment 19 kinetics the study of a chemical reaction Results Part A I- / counterspy dm-3 S2O82- / mol dm-3 S2O32- / mol dm-3 term /s rate of I2 formation / mol dm-3 s-1 0. 2 0. 2 0. 01 1. 25 0. 1600 0. 2 0. 15 0. 01 13. 37 0. 0150 0. 2 0. 10 0. 01 26. 00 0. 0077 0. 2 0. 05 0. 01 66. 5 0. 00075 Part B I- / mol dm-3 S2O82- / mol dm-3 S2O32- / mol dm-3 Time /s Rate of I2 formation / mol dm-3 0. 2 0. 2 0. 01 3. 45 0. 0580 0. 15 0. 2 0. 01 7. 56 0. 0198 0. 10 0. 2 0. 01 9. 06 0. 0110 0. 05 0. 2 0. 01 23. 91 0. 0021 Part C Initial temperature/ OC Final temperature/ OC Time t /s Rate of I2 formation / mol dm-3 1/T (1/K) Log t 15 21 29 0. 00690 0. 003472 1. 462 24 25 20 0. 01000 0. 003367 1. 301 35 42 13 0. 01538 0. 003247 1. 114 45 40 8 0. 02500 0. 003145 0. 903 Calculations & QuestionsAssociated essay measurement reply Rate Using Volume of Gas ProducedThe effect of temperature is that it increases the value of reaction, observed here by the higher temperatures giving a a lot spryer reaction time a) Is reaction (2) fast or dense with respect to reaction (1)? Explain your reasoning or record any(prenominal) test you do to help r for each one your conclusion Reaction (2) is fast with respect to reaction (1). Reaction (2) I2+2 S2O32- 2 I-+ S4O62- occurs extremely fast, I2 organize in the reaction is consumed immediately and when the limiting agent S2O32- is used up, I2 reacts with the amylum indicator to form a blue color reply. ) Does reaction (1) or (2) control the time required for the blue colour to appear? Reaction (1) 2I-+ S2O82-I2+2SO42- controls the time required for the blue colour to appear as it is the I2 that forget react with the starch indicator to produce the blue color upshot to appear c) Calculate the browse of formation of I2 in mol dm-3 s-1 for each experiment at room temperature and plot this rate i) Against S2O82- at regular I- ii) Against I- at constant S2O82- The rate of formation of I2 can be metrical by calculating of the rate of change of the thiosulphate ion over the time taken Rate of formation of I2=? I2t d) What are the shapes of these plots? They are straight line interprets ,with the y axis directly proportional to the x axis e) What is the significance of this? This shows that the rate is directly proportional to the concentration of I- and S2O82- and by calculating the gradient of the graph we will obtain the rate of reaction. f) Write the rate equation for reaction (1) dI2dt=kS2O82- And calculate the rate constant , k Rate = kI-S2O82- k = Rate / I-S2O82- k = slope / S2O82- k = (0. 015-0. 0008)/(0. 15-0. 05)Rate constant k = 0. 142 mol-1 dm3 s-1 g) Calculate the free energy of activation of the reaction If we plot a graph of log t against 1/T, we can obtain the Ea by calculating the slope. Slope of the graph = Ea / 2. 303R Ea / 2. 303R = (1. 462-0. 903)(0. 003472-0. 003145) Ea / 2. 303R = 0. 559/(3. 2710-4) Ea = 1709. 48 x 2. 303R Ea = 1709. 48 x 2. 303 x 8. 314 Ea = 32731. 65 J/mol Discussion Precautions Among some of the precautions taken were to wear gloves , base hit goggles and lab coats to avoid any injury in slick of exposure to chemicals.Secondly, there were separate criterion cylinders prepared for each solution as to not mix 2 solutions in a measuring cylinder to avoid any reactions. The persulphate was poured in rapidly as this is an extremely fast step and has to be poured all at once. Finally,when diluting the persulphate solution, it was done as accurately as possible in order to avoid a wrong concentration instead of the one intended. Conclusion Based on the experiment done as swell as the analysis of the results and aft(prenominal) doing further results, we have learned that the activat ion energy of the reaction is 32. 73 kJ.Furthermore, we have gained an insight into the kinetics of a reaction, its rate, the rate constants as well as the rate of reaction. References Martin S. Silberberg, Chemistry the Molecular Nature of Matter and Change, one-fifth Edition, McGraw Hill, 2005. F. Albert Cotton, Geoffrey Wilkinson, Carlos A. Murillo, and Manfred Bochmann, Advanced inorganic Chemistry, one-sixth edition, John Wiley& Son. 1999. F. Albert Cotton, Geoffrey Wilkinson, Paul L. Gaus, Basic Inorganic Chemistry, Third Edition, John Wiley& Son. 1995. John C. Kotz, Paul M. Treichel, and Gabriela C. Weaver, Chemistry and Chemical Reactivity, Sixth Edition, Thomson 2006.